On my PC, the password suggestion list suggests every password from every domain when the username field is automatically pre-filled, instead of the saved password for the username.
When I delete one character, it correctly suggests the matching name and password.
In the little info-bit of your Original Post, above, you wrote:
“Linux Mint Una 20, Brave Version 1.68.128 Chromium: 127.0.6533.73 (Official Build) (64-bit)”
Brave Support needs to know the most recent version of Brave Browser that you are now using.
Please edit/fix up your Original Post and attempt to follow the Brave Support guidelines for submitting a bug report (Official Brave Help Center article):